P. Rebeyrollebernard et P. Etievant, VOLATILE COMPOUNDS EXTRACTED FROM POLYPROPYLENE SHEETS BY HOT-WATER -INFLUENCE OF THE TEMPERATURE OF SHEETS INJECTION, Journal of applied polymer science, 49(7), 1993, pp. 1159-1164
The influence of the formulation of polypropylene (PP) on the organole
ptic properties of the foodstuff in contact is of great importance for
the quality of the product. A study was made on PP pellets degraded a
nd not degraded and pointed out the presence and olfactive importance
of volatile components extracted from PP pellets by hot water. Plastic
packaging materials correspond to a further step of manufacturing: th
e injection step, and this is often conducted at high temperature. PP
(not degraded) and PP-CR (degraded) were transformed into sheets at se
veral temperatures; Lickens-Nickerson extracts were made and allowed t
he quantification of volatile compounds already identified. A statisti
cal analysis showed that temperature was a very significant parameter.
An increasing injection temperature (275 or 300-degrees-C) creates in
creasing quantities of volatiles. This was well correlated with the se
nsory analysis made on the organic extracts of the sheets and also dir
ectly on molded cups. (C) 1993 John Wiley & Sons, Inc.