Sn. Chvalun et al., ETCHING OF HIGHLY ORIENTED POLYETHYLENE B Y FUMING NITRIC-ACID, Vysokomolekularnye soedinenia. Seria A, 35(6), 1993, pp. 10000640-10000645
Structural changes in oriented polyethylene etched with fuming nitric
acid were studied by X-ray diffraction measurements. Samples of variou
s molecular masses and drawn to different drawing ratios were consider
ed. Prolonged etching (up to 200 h), caused considerable changes in th
e small-angle X-ray scattering patterns, notably, additional broad ref
lection appeared. This reflection is assumed to be attributable to the
presence in the polymer of a broad distribution of distances between
the entanglements (the reactivity of the entanglements is higher than
that of the remaining polymer) of the polymer network.