KINETIC-PARAMETERS OF DEHYDROCHLORINATION OF POLYVINYL-CHLORIDE IN SOLUTION

Citation
Ks. Minsker et al., KINETIC-PARAMETERS OF DEHYDROCHLORINATION OF POLYVINYL-CHLORIDE IN SOLUTION, Vysokomolekularnye soedinenia. Seria A, 35(6), 1993, pp. 20000316-20000318
Citations number
9
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
35
Issue
6
Year of publication
1993
Pages
20000316 - 20000318
Database
ISI
SICI code
0507-5475(1993)35:6<20000316:KODOPI>2.0.ZU;2-U
Abstract
The kinetics of thermal degradation of PVC in the presence of solvents (plasticizers) depends on the basicity of the solvent. The kinetic pa rameters of the process depend on the interaction between functional g roups of the solvent and polymer molecules, i.e. on the specific solva tion of a polymer with a solvent. An equation describing the rate of e limination of HCl from PVC in solution is proposed.