1,4-CYCLOADDITION REACTIONS OF SULFUR-CON TAINING AND OXYGEN-CONTAINING CYCLIC GERMYLENES WITH 1,3-HETEROBUTADIENES CONTAINING SILICON OR GERMANIUM AND WITH 3,5-DI-T-BUTYLORTHOQUINONE

Citation
C. Laurent et al., 1,4-CYCLOADDITION REACTIONS OF SULFUR-CON TAINING AND OXYGEN-CONTAINING CYCLIC GERMYLENES WITH 1,3-HETEROBUTADIENES CONTAINING SILICON OR GERMANIUM AND WITH 3,5-DI-T-BUTYLORTHOQUINONE, Journal of organometallic chemistry, 452(1-2), 1993, pp. 41-45
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
452
Issue
1-2
Year of publication
1993
Pages
41 - 45
Database
ISI
SICI code
0022-328X(1993)452:1-2<41:1ROSTA>2.0.ZU;2-G
Abstract
Cycloaddition reactions of 1,2-dithiolane or 1,2-oxathiolanegermanediy ls with 3,4-bis(methylene)sila- and germacycloalkanes are reported. Si milarly, 3,5-di t-butylorthoquinone undergoes 1,4-cycloaddition with t hese heterocyclic germylenes. The reactivity of some new dimetalapenta lenes with bromine or dichlorodicyanoquinone (DDQ) is also described.