SYNTHESIS AND PROPERTIES OF A ZIRCONACYCL OBUTANE DERIVATIVE

Authors
BOHME U THIELE KH
Citation
U. Bohme et Kh. Thiele, SYNTHESIS AND PROPERTIES OF A ZIRCONACYCL OBUTANE DERIVATIVE, Journal of organometallic chemistry, 452(1-2), 1993, pp. 75-78
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
452
Issue
1-2
Year of publication
1993
Pages
75 - 78
Database
ISI
SICI code
0022-328X(1993)452:1-2<75:SAPOAZ>2.0.ZU;2-J
Abstract
The zirconacyclobutane derivative (tritox)2ZrC(=CH2)CH2CH2 (tritox = ( t-C4H9)3CO) with exocyclic methylidine group is formed unexpectedly fr om (tritox)2ZrCl2 and vinyllithium. The compound was characterized by H-1 and C-13 NMR spectra. The reaction mechanism is discussed. The Zr- 91 NMR spectrum of (tritox)2ZrCl2 is reported.