H-1-NMR SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN CYCLODEXTRINS AND BICYCLO[3.3.1]NONANES

Authors
BUTKUS E MARTINS JC BERG U
Citation
E. Butkus et al., H-1-NMR SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN CYCLODEXTRINS AND BICYCLO[3.3.1]NONANES, Journal of inclusion phenomena and molecular recognition in chemistry, 26(4), 1996, pp. 209-218
Citations number
16
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
26
Issue
4
Year of publication
1996
Pages
209 - 218
Database
ISI
SICI code
0923-0750(1996)26:4<209:HSSOTI>2.0.ZU;2-9
Abstract
The formation and structure of inclusion complexes of 2,6- and 2,9-sub stituted bicyclo[3.3.1]nonanes with alpha- and beta-cyclodextrin (CD) has been investigated by high-resolution H-1 NMR spectroscopy. alpha- and P-CD were found to form 1:1 inclusion complexes and the binding co nstants were estimated from titration studies. 2D ROESY experiments pr ovided insight into the structure of the complexes.