TRANSITION-METAL MEDIATED ASYMMETRIC-SYNTHESIS .14. A NEW STRATEGY FOR THE REACTIVATION OF TRICARBONYLIRON COMPLEXES

Authors
ALEXANDER IJ HALES NJ STEPHENSON GR
Citation
Ij. Alexander et al., TRANSITION-METAL MEDIATED ASYMMETRIC-SYNTHESIS .14. A NEW STRATEGY FOR THE REACTIVATION OF TRICARBONYLIRON COMPLEXES, Journal of organometallic chemistry, 453(1), 1993, pp. 111-115
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
453
Issue
1
Year of publication
1993
Pages
111 - 115
Database
ISI
SICI code
0022-328X(1993)453:1<111:TMA.AN>2.0.ZU;2-P
Abstract
Protonation of an exo-substituted eta4-triene complex results in a hyd rogen shift that removes the effect of a blocking group and so provide s a means of regenerating the eta5-cation in situations in which hydri de abstraction would be prevented by the exo-substituent.