OXIDATION OF 1-METHYLCYCLOBUTANOL BY PB(IV) AND MN(III) COMPOUNDS

Authors
KAPUSTINA NI NIKISHIN GI
Citation
Ni. Kapustina et Gi. Nikishin, OXIDATION OF 1-METHYLCYCLOBUTANOL BY PB(IV) AND MN(III) COMPOUNDS, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(12), 1992, pp. 2189-2192
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
12
Year of publication
1992
Part
2
Pages
2189 - 2192
Database
ISI
SICI code
1063-5211(1992)41:12<2189:OO1BPA>2.0.ZU;2-Y
Abstract
The main product of the reaction of 1-methylcyclobutanol with Pb(OAC)4 in benzene is 1-phenyl-4-pentanone; the use of Mn(OAc)3 in acetic aci d gives a mixture of 2,9-decanedione and methyl propyl ketone; 1-(chlo ro-, bromo-, thiocyano-, or cyano)-4-pentanone is formed in the presen ce of the systems Pb(OAC)4 - metal halide or Mn(OAc)3-metal halide.