In this paper, it is reported that the electroluminescence (EL) of por
ous silicon shows a reversible spectral shift as large as 270 nm for a
n external bias variation of 0.6 V. This electroluminescence is obtain
ed upon cathodic polarization of lightly doped n-type porous silicon i
n contact with aqueous persulphate solutions. The study of the EL beha
vior as a function of the external voltage and the persulphate ion con
centration proves that while the amplitude of the EL is proportional t
o the intensity of the exchanged current, the spectral position is onl
y determined by the applied voltage.