A concise review on the basic principles and methodology used in spect
roscopic ellipsometry analysis is presented. The technique is truly no
n-destructive and allows optical and structural parameters to be acces
sed in a wide range of problems in materials research. Several recent
examples are presented. These include the structural analysis of high-
dose oxygen-implanted silicon substrates, the determination of the opt
ical constants of thin ZnSe films on c-GaAs grown by molecular beam ep
itaxy and the determination of the Ge content in Si1-xGex alloy films
on c-Si grown by chemical vapour deposition.