Bu. Felderhof et Rb. Jones, SEPARATION OF TIME SCALES IN SPECIES CONVERSION BY DIFFUSION-CONTROLLED REACTIONS IN A BINARY SUSPENSION OF SPHERES, The Journal of chemical physics, 106(12), 1997, pp. 5006-5012
Transient diffusion-controlled reactions in a binary suspension of equ
al-sized spheres are studied in a region of the equilibrium phase diag
ram, where a separation of time scales occurs. In Ising model language
, the suspension consists of hard spheres with an internal classical s
pin taking two values, with a square well Ising interaction and with a
magnetic field present. Transitions can occur whenever a pair of sphe
res approaches within the range of the Ising interaction. A separation
of time scales is observed near the ferromagnetic phase transition. T
his allows a simplified phenomenological description of the relaxation
of magnetization. (C) 1997 American Institute of Physics.