SEPARATION OF TIME SCALES IN SPECIES CONVERSION BY DIFFUSION-CONTROLLED REACTIONS IN A BINARY SUSPENSION OF SPHERES

Citation
Bu. Felderhof et Rb. Jones, SEPARATION OF TIME SCALES IN SPECIES CONVERSION BY DIFFUSION-CONTROLLED REACTIONS IN A BINARY SUSPENSION OF SPHERES, The Journal of chemical physics, 106(12), 1997, pp. 5006-5012
Citations number
7
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
106
Issue
12
Year of publication
1997
Pages
5006 - 5012
Database
ISI
SICI code
0021-9606(1997)106:12<5006:SOTSIS>2.0.ZU;2-O
Abstract
Transient diffusion-controlled reactions in a binary suspension of equ al-sized spheres are studied in a region of the equilibrium phase diag ram, where a separation of time scales occurs. In Ising model language , the suspension consists of hard spheres with an internal classical s pin taking two values, with a square well Ising interaction and with a magnetic field present. Transitions can occur whenever a pair of sphe res approaches within the range of the Ising interaction. A separation of time scales is observed near the ferromagnetic phase transition. T his allows a simplified phenomenological description of the relaxation of magnetization. (C) 1997 American Institute of Physics.