CIS-DERIVED AND TRANS-DERIVED CHAIN STACKING IN BIS(HEXAFLUOROACETYLACETONATO)METAL(II) TETRAMETHYLPYRAZINE COMPLEXES

Authors
ADAMS H BAILEY NA FENTON DE KHALIL RA
Citation
H. Adams et al., CIS-DERIVED AND TRANS-DERIVED CHAIN STACKING IN BIS(HEXAFLUOROACETYLACETONATO)METAL(II) TETRAMETHYLPYRAZINE COMPLEXES, Inorganica Chimica Acta, 209(1), 1993, pp. 55-60
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
209
Issue
1
Year of publication
1993
Pages
55 - 60
Database
ISI
SICI code
0020-1693(1993)209:1<55:CATCSI>2.0.ZU;2-P
Abstract
The reaction of metal(II) hexafluoroacetylacetonates (meta]=Mn(II), Fe (II), Co(II), Ni(II), Cu(II), Zn(II)) with tetramethylpyrazine is repo rted. The X-ray crystal structures of [Mn(hfac)2]2(tmp)3.4H2O and Co(h fac)2(tmp).4H2O are reported and reveal the formation of chain polymer s through second sphere cis- and trans-derived stacking, respectively.