PRACTICAL VERSION OF THE ASYMPTOTIC LINEARITY THEOREM WITH APPLICATIONS TO THE ADDITIVITY PROBLEMS OF THERMODYNAMIC QUANTITIES

Citation
S. Arimoto et K. Taylor, PRACTICAL VERSION OF THE ASYMPTOTIC LINEARITY THEOREM WITH APPLICATIONS TO THE ADDITIVITY PROBLEMS OF THERMODYNAMIC QUANTITIES, Journal of mathematical chemistry, 13(3-4), 1993, pp. 265-272
Citations number
34
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
13
Issue
3-4
Year of publication
1993
Pages
265 - 272
Database
ISI
SICI code
0259-9791(1993)13:3-4<265:PVOTAL>2.0.ZU;2-Q
Abstract
By using fundamental notions and theorems of the Lesbesgue integral, a practical version of the Asymptotic Linearity Theorem has been derive d. From this new version of the theorem, it easily follows that the th eorem is also applicable to the additivity problems of thermodynamic q uantities of molecules having many identical moieties, as well as to t hose of the zero-point vibrational energy of hydrocarbons and the tota l pi-electron energies of alternant hydrocarbons.