SYNTHESIS AND STRUCTURE OF NEW DERIVATIVES OF THIENO[2,3-B]THIOCINE -UNUSUAL INTRAMOLECULAR CYCLOADDITION PRODUCT OF 2-HOMOMETHALLYL-3-THIOPHENECARBONITRILE OXIDE

Citation
Mm. Krayushkin et al., SYNTHESIS AND STRUCTURE OF NEW DERIVATIVES OF THIENO[2,3-B]THIOCINE -UNUSUAL INTRAMOLECULAR CYCLOADDITION PRODUCT OF 2-HOMOMETHALLYL-3-THIOPHENECARBONITRILE OXIDE, Mendeleev communications, (3), 1993, pp. 114-115
Citations number
7
Categorie Soggetti
Chemistry
Journal title
ISSN journal
09599436
Issue
3
Year of publication
1993
Pages
114 - 115
Database
ISI
SICI code
0959-9436(1993):3<114:SASOND>2.0.ZU;2-G
Abstract
For the first time 5,6-hexahydrothieno[2,3-b]thiocine[4,5-c]isoxazole and o-3,4,6-hexahydro-5-methylenethieno[2,3-b]thiocine have been prepa red by NaOCl oxidation of 2-omega-alkenylthio-3-thiophenecarbal-doxime s. The structure of these products has been confirmed by mass, H-1 NMR and C-13 NMR spectroscopy, and of the second, also by X-ray analysis.