SOLVENT EFFECTS IN THE REACTIVITY OF PHENYLETHYL HYDROPEROXIDE .2. REACTIVITY AND BETA-SCISSION OF ALPHA-PHENYLETHOXY RADICALS IN THE SOLUTIONS OF ALPHA-PHENYLETHYLHYDROPEROXIDE

Authors
MOGER G MAZALECZKAJA LI GAL D
Citation
G. Moger et al., SOLVENT EFFECTS IN THE REACTIVITY OF PHENYLETHYL HYDROPEROXIDE .2. REACTIVITY AND BETA-SCISSION OF ALPHA-PHENYLETHOXY RADICALS IN THE SOLUTIONS OF ALPHA-PHENYLETHYLHYDROPEROXIDE, Reaction kinetics and catalysis letters, 49(1), 1993, pp. 135-138
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
49
Issue
1
Year of publication
1993
Pages
135 - 138
Database
ISI
SICI code
0133-1736(1993)49:1<135:SEITRO>2.0.ZU;2-1
Abstract
Efficient cleavage of alpha-phenylethoxy radicals (HRO.) was observed in CH3CN at 304 K. From measurements of the quantum yields of product formation, it was calculated that (k)HRO. + HROOH/k(beta) = 36+/-3 M-1 .