A SACM STUDY OF THE CROSS-COMBINATION RATIO OF RATE CONSTANTS

Authors
COBOS CJ
Citation
Cj. Cobos, A SACM STUDY OF THE CROSS-COMBINATION RATIO OF RATE CONSTANTS, Reaction kinetics and catalysis letters, 49(1), 1993, pp. 167-171
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
49
Issue
1
Year of publication
1993
Pages
167 - 171
Database
ISI
SICI code
0133-1736(1993)49:1<167:ASSOTC>2.0.ZU;2-5
Abstract
An analysis of the cross-combination ratio of the rate constants phi i n terms of the statistical adiabatic channel model allows to factorize phi into two contributions: one due to the motion along the reaction coordinates and another due to the reaction transitional modes. Phi fo r the CH3/CCl3, CH3/C2H3, CH3/C3H5, CH3/C2H5 and C2H5/C3H5 radical pai rs were calculated.