DEMS AND IN-SITU FTIR INVESTIGATIONS OF C3 PRIMARY ALCOHOLS ON PLATINUM-ELECTRODES IN ACID-SOLUTIONS .2. ALLYL ALCOHOL

Authors
PASTOR E WASMUS S IWASITA T AREVALO MC GONZALEZ S ARVIA AJ
Citation
E. Pastor et al., DEMS AND IN-SITU FTIR INVESTIGATIONS OF C3 PRIMARY ALCOHOLS ON PLATINUM-ELECTRODES IN ACID-SOLUTIONS .2. ALLYL ALCOHOL, Journal of electroanalytical chemistry [1992], 353(1-2), 1993, pp. 81-100
Citations number
39
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
353
Issue
1-2
Year of publication
1993
Pages
81 - 100
Database
ISI
SICI code
Abstract
On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spec troscopy (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in ac ids. The electroreduction products were propanol and a mixture of prop ylene, propane and ethane. The main oxidation products were CO2 and ac rolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths an d structures.