THIOMETHYLATION OF THE METAL-CARBON MULTI PLE BOND OF CARBYNE AND CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN

Authors
KREISSL FR SCHUTT W STEGMAIR CM ULLRICH N KELLER H OSTERMEIER J HERDTWECK E
Citation
Fr. Kreissl et al., THIOMETHYLATION OF THE METAL-CARBON MULTI PLE BOND OF CARBYNE AND CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN, Chemische Berichte, 126(7), 1993, pp. 1609-1614
Citations number
53
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
126
Issue
7
Year of publication
1993
Pages
1609 - 1614
Database
ISI
SICI code
0009-2940(1993)126:7<1609:TOTMMP>2.0.ZU;2-D
Abstract
Carbyne complexes of molybdenum and tungsten react with dialkyl(methyl thio)sulfonium tetrafluoroborate in a stepwise addition of the alkylth io cation to the metal-carbon multiple bond yielding dicationic eta3-d ithiomethyl complexes.