DOUBLE SULFUR TRANS INFLUENCE IN THE DITHIOLATO COMPLEX - TRANS(S)-[CO(AET)2(EN)]CLO4 (AET = 2-AMINOETHANETHIOLATE)

Authors
YONEMURA T OKAMOTO K AMA T KAWAGUCHI H YASUI T
Citation
T. Yonemura et al., DOUBLE SULFUR TRANS INFLUENCE IN THE DITHIOLATO COMPLEX - TRANS(S)-[CO(AET)2(EN)]CLO4 (AET = 2-AMINOETHANETHIOLATE), Chemistry Letters, (7), 1993, pp. 1123-1126
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1993
Pages
1123 - 1126
Database
ISI
SICI code
0366-7022(1993):7<1123:DSTIIT>2.0.ZU;2-U
Abstract
The title aliphatic thiolato complex, whose trans positions were occup ied by two sulfur atoms, was newly prepared and its crystal structure was determined by the X-ray diffraction study. The Co-S bond distances in that complex are longer than the ordinary one. Reaction of the com plex at 50-degrees-C in water gave cis(S)-[Co(aet)2(en)]+ and trinucle ar complex, [Co{Co(aet)3}2]3+.