NOVEL SYNTHESES OF 1,2-DIARYLACETYLENES AND ALPHA-SILYALCOHOLS FROM ACYLSILANES MEDIATED BY YTTERBIUM METAL

Authors
TANIGUCHI Y FUJII N MAKIOKA Y TAKAKI K FUJIWARA Y
Citation
Y. Taniguchi et al., NOVEL SYNTHESES OF 1,2-DIARYLACETYLENES AND ALPHA-SILYALCOHOLS FROM ACYLSILANES MEDIATED BY YTTERBIUM METAL, Chemistry Letters, (7), 1993, pp. 1165-1168
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1993
Pages
1165 - 1168
Database
ISI
SICI code
0366-7022(1993):7<1165:NSO1AA>2.0.ZU;2-G
Abstract
Aromatic acylsilanes such as benzoyltrimethylsilane react with ytterbi um metal to give symmetrical 1, 2-diarylacetylenes in good yields. Ali phatic acylsilanes are reduced with lanthanoid reagents such as Yb met al and SmI2 to afford alpha-silylalcohols.