B. Wisniewska et al., DEVELOPMENT OF A VAPOR-LIQUID-EQUILIBRIUM APPARATUS TO WORK AT PRESSURES UP TO 3 MPA, Fluid phase equilibria, 86, 1993, pp. 173-186
An apparatus for vapour - liquid equilibrium measurement at elevated p
ressures was built. Construction was based on the Rogalski - Malanowsk
i glass ebulliometer designed for precise measurements up to normal pr
essure. Experimental procedure was also developed. For the performance
test of the proposed apparatus the vapour pressure was measured for f
our pure substances (benzene, heptane, cyclohexane and water) and the
vapour - liquid equilibrium (VLE) was determined for two binary mixtur
es (benzene + heptane and benzene + cyclohexane). The results obtained
were satisfactory.