ELECTRONIC DECAY OF VIBRATIONALLY SELECTED CORE-EXCITED STATES IN MOLECULAR N(2)

Authors
RUBENSSON JE NEEB M BIERMANN M XU Z EBERHARDT W
Citation
Je. Rubensson et al., ELECTRONIC DECAY OF VIBRATIONALLY SELECTED CORE-EXCITED STATES IN MOLECULAR N(2), The Journal of chemical physics, 99(3), 1993, pp. 1633-1636
Citations number
14
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
99
Issue
3
Year of publication
1993
Pages
1633 - 1636
Database
ISI
SICI code
0021-9606(1993)99:3<1633:EDOVSC>2.0.ZU;2-2
Abstract
We have measured and analyzed the vibrational fine structure of the el ectronic participator decay of the 1s-1 1pi(g) state in gas-phase N2. The monochromator resolution allowed us to limit the vibrational excit ations in the excited state so that unequivocally assignable vibration al fine structure in the decay spectra could be resolved. The excitati on-emission process is shown to be well-described within the two-step Franck-Condon model, and the data represents individual decay of vibra tionally selected core excited states.