AN IMPROVED SYNTHESIS OF PERFLUOROALKYL ALDEHYDES FROM THE REACTION OF PERFLUOROALKYL IODIDES WITH DIMETHYLFORMAMIDE

Authors
BENEFICEMALOUET S BLANCOU H COMMEYRAS A
Citation
S. Beneficemalouet et al., AN IMPROVED SYNTHESIS OF PERFLUOROALKYL ALDEHYDES FROM THE REACTION OF PERFLUOROALKYL IODIDES WITH DIMETHYLFORMAMIDE, Journal of fluorine chemistry, 63(3), 1993, pp. 217-226
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
63
Issue
3
Year of publication
1993
Pages
217 - 226
Database
ISI
SICI code
0022-1139(1993)63:3<217:AISOPA>2.0.ZU;2-U
Abstract
The reactivity of perfluoroalkyl iodide in the presence of a zinc-copp er metal couple and a radical initiator in DMF, has been investigated. This led to the formation of a mixture of N,N-dimethyl perfluoroalkyl amide and perfluoroalkyl aldehyde. After studying the influence of dif ferent reaction parameters, the perfluoroalkyl aldehyde formation has been optimized to high yield (over 90%).