The ferroelectric domain wall is an ideal interface for studies of the
boundary scattering of high frequency acoustic phonons. These interna
l interfaces have no contamination and can be reversibly created and d
estroyed by application of an electric field at the phase transition-
122 K in KDP. Images of phonons in single- and multiple-domain cases s
how remarkable differences in the ballistic heat flux. Theoretical mod
eling based on acoustic wave reflection reveals that the domain walls
act as nearly perfect grain boundaries.