The electrocatalytic oxidation of saccharose solutions was carried out
in alkaline medium on various noble and non-noble electrodes, with th
e aim of checking the electroreactivity of saccharose and its potentia
lity as a raw material for electrosynthesis. The best electrocatalytic
activity was obtained with gold. In this latter case, chromatographic
analysis of electrolysed solutions allowed us to identify numerous mo
nocarboxylic acids, some of them resulting from the breaking of the C-
O-C bond.