The morphology of TiN thin films on a steel surface produced by the pr
ocess of laser ablation has been investigated. The process involves ma
terial removal from a titanium target by means of an ultraviolet excim
er pulse laser. Both the target and the steel substrate are in an ammo
nia atmosphere and therefore the titanium atoms react with the nitroge
n under the influence of a laser-induced plasma, and the product, whic
h is TiN, is deposited on the surface of the steel. The investigation
revealed that at the beginning of the process the TiN film is uniform;
however, with increasing number of pulses, small micrometre-sized par
ticles begin to appear on the surface and after a large number of puls
es all the surface is covered with these particles.