D. Minick et al., CRYSTAL AND MOLECULAR-STRUCTURE OF [CPRU(PPH3)2(T-C4H9SH)]BF4, Journal of crystallographic and spectroscopic research, 23(8), 1993, pp. 629-632
The structure of the [CpRu(PPh3)2(t-C4H9SH)]BF4 complex was determined
by X-ray diffraction techniques: monoclinic space group P2(1)/c, a =
14.662(9), b = 18.515(7), c = 15.368(6)angstrom, beta = 101.88(5)-degr
ees, V = 4082(6)angstrom3, Z = 4, R = 0.049, R(w) = 0.057. The Ru is a
ttached to two tfiphenylphosphine ligands, a cyclopentadienyl and the
t-butylmercaptan. The Ru-S distance is 2.396(2)angstrom and the S-H di
stance is 1.289(2)angstrom.