CRYSTAL AND MOLECULAR-STRUCTURE OF [CPRU(PPH3)2(T-C4H9SH)]BF4

Authors
MINICK D DRAGANJAC M CRUMP JW CORDES AW
Citation
D. Minick et al., CRYSTAL AND MOLECULAR-STRUCTURE OF [CPRU(PPH3)2(T-C4H9SH)]BF4, Journal of crystallographic and spectroscopic research, 23(8), 1993, pp. 629-632
Citations number
15
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of crystallographic and spectroscopic research → ACNP
ISSN journal
02778068
Volume
23
Issue
8
Year of publication
1993
Pages
629 - 632
Database
ISI
SICI code
0277-8068(1993)23:8<629:CAMO[>2.0.ZU;2-T
Abstract
The structure of the [CpRu(PPh3)2(t-C4H9SH)]BF4 complex was determined by X-ray diffraction techniques: monoclinic space group P2(1)/c, a = 14.662(9), b = 18.515(7), c = 15.368(6)angstrom, beta = 101.88(5)-degr ees, V = 4082(6)angstrom3, Z = 4, R = 0.049, R(w) = 0.057. The Ru is a ttached to two tfiphenylphosphine ligands, a cyclopentadienyl and the t-butylmercaptan. The Ru-S distance is 2.396(2)angstrom and the S-H di stance is 1.289(2)angstrom.