ORGANOMETALLIC COMPOUNDS FOR NONLINEAR OPTICS - SYNTHESIS, REACTIVITYAND ELECTROCHEMISTRY OF CHIRAL ETA-5-MONOCYCLOPENTADIENYL(NITRILE) IRON COMPLEXES

Authors
DIAS AR GARCIA MH ROBALO MP GREEN MLH LAI KK PULHAM AJ KLUEBER SM BALAVOINE G
Citation
Ar. Dias et al., ORGANOMETALLIC COMPOUNDS FOR NONLINEAR OPTICS - SYNTHESIS, REACTIVITYAND ELECTROCHEMISTRY OF CHIRAL ETA-5-MONOCYCLOPENTADIENYL(NITRILE) IRON COMPLEXES, Journal of organometallic chemistry, 453(2), 1993, pp. 241-247
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
453
Issue
2
Year of publication
1993
Pages
241 - 247
Database
ISI
SICI code
0022-328X(1993)453:2<241:OCFNO->2.0.ZU;2-U
Abstract
A new family of compounds of general formula [FeCp ((+)-DIOP)(p-NCC6H4 R')][PF6] (R'= donor or acceptor group) was synthesized and characteri zed for non-linear optical properties. Spectroscopic (IR and H-1 C-13 and P-31 NMR) and electrochemical (cyclic voltammetry) studies are con sistent with charge-transfer from Fe(II) to coordinated benzonitrile v ia d-pi back donation. One compound of this family, [FeCp((+)-DIOP)(p -NCC6H4NO2)][PF6] has an SHG value 38 times greater than that of urea.