COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6]

Authors
DEMIRHAN F IRISLI S SALEK SN SENTURK OS WENT MJ JEFFERY JC
Citation
F. Demirhan et al., COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6], Journal of organometallic chemistry, 453(2), 1993, pp. 30000030-30000031
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
453
Issue
2
Year of publication
1993
Pages
30000030 - 30000031
Database
ISI
SICI code
0022-328X(1993)453:2<30000030:COCASB>2.0.ZU;2-Z
Abstract
The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(C O)6(AgPPh3)][BF4], the structure of which has been established by X-ra y crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH 2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitut ion.