C. Hubschmid et al., PASSIVE FILM COMPOSITION AND PITTING BEHAVIOR OF FE-25CR-11NB STUDIEDBY SCANNING AUGER MICROSCOPY, Surface and interface analysis, 20(9), 1993, pp. 755-760
Scanning Auger microscopy has been applied to the characterization of
passive films formed on an Fe-25Cr-11 Nb model alloy having a dendriti
c structure. The composition of the passive film is spatially non-unif
orm and reflects the phase structure of the alloy. The Fe-25Cr-11Nb al
loy exhibited a better resistance to pitting than a binary Fe-25Cr all
oy. This is due to the fact that, on one hand, niobium improves the pi
tting resistance of the niobium-rich phase while, on the other hand, t
he pitting resistance of the niobium-poor phase is enhanced by chromiu
m segregation.