U. Gorl et R. Panenka, SILANIZED SILICAS - A NEW PRODUCT RANGE F OR MODERN COMPOUND DEVELOPMENT, Kautschuk und Gummi, Kunststoffe, 46(7), 1993, pp. 538-544
Today, bifunctional organosilanes are used in many rubber compounds. T
hey react with the filler on the one hand, and with the polymer on the
other The formation of filler-rubber linkages via organosilanes has a
major influence on the properties of rubber compounds. In conventiona
l technology the reaction between filler and silane takes place in the
rubber-filler batch during compounding. This in situ modification req
uires a number of precautions regarding the mixing sequence and mixing
temperature, as well as the careful adjustment of mixing conditions f
or every silane-containing compound. In silanized silicas, the silane
has already undergone a chemical reaction with the silica which render
s the above precautions superfluous. Silanized silicas can be used lik
e conventional fillers. This paper compares eight different types of s
ilanized silicas, based on silicas with different N2 surface areas and
silanes with different chemical constitutions, describes their in-rub
ber properties and points out their differences.