THE STRUCTURE OF CARBOXYL-CONTAINING POLY URETHANES CURED WITH METAL-IONS (II)

Authors
NIZELSKII YN KOSYANCHUK LF LIPATOV YS ROSOVITSKII VF PRIVALKO EG MASLAK YV
Citation
Yn. Nizelskii et al., THE STRUCTURE OF CARBOXYL-CONTAINING POLY URETHANES CURED WITH METAL-IONS (II), Vysokomolekularnye soedinenia. Seria A, 35(7), 1993, pp. 10000793-10000797
Citations number
12
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
35
Issue
7
Year of publication
1993
Pages
10000793 - 10000797
Database
ISI
SICI code
0507-5475(1993)35:7<10000793:TSOCPU>2.0.ZU;2-A
Abstract
Barium- and lead- containing polyurethanes were synthesized. The chemi cal bonding of metals was confirmed by IR spectroscopy. The effect of metal ions on the microstructure of polymers was measured by different ial scanning calorimetry and dynamic mechanical spectroscopy. The stru cture of ion-cured polymers was found to be determined not by the type of metal-polymer bonding, but by the ability of metal ions to partici pate in additional donor-acceptor interactions. For some systems the e nergy of these interactions can exceed the energy of the metal-polymer ionic bonds.