KINETICS OF CYCLIZATION IN THE PROCESS OF IRREVERSIBLE LINEAR CONDENSATIONAL POLYMERIZATION

Authors
IRZHAK TF PEREGUDOV NI IRZHAK VI ROZENBERG BA
Citation
Tf. Irzhak et al., KINETICS OF CYCLIZATION IN THE PROCESS OF IRREVERSIBLE LINEAR CONDENSATIONAL POLYMERIZATION, Vysokomolekularnye soedinenia. Seria A, 35(7), 1993, pp. 20000905-20000908
Citations number
10
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
35
Issue
7
Year of publication
1993
Pages
20000905 - 20000908
Database
ISI
SICI code
0507-5475(1993)35:7<20000905:KOCITP>2.0.ZU;2-J
Abstract
The kinetics of cyclization in the process of irreversible linear cond ensational polymerization was studied numerically. The dependence of t he kinetics of accumulation of cycles on the kinetic constants of cycl ization and second addition was analyzed. The effect of kinetic limit of cycle accumulation was shown to occur for comparatively low cycliza tion constants. The dependence of the accumulation of cyclic products of condensational polymerization on the dilution was considered.