We have successfully synthesized heterojunctions and elementary multil
ayered structures of the semimetal-semiconductor system Sb/GaSb using
molecular beam and migration enhanced epitaxies. The study is motivate
d in part by the potential for producing an indirect narrow-gap semico
nductor, in which a confinement-induced positive energy gap in the Sb
layers will lead to highly attractive properties for nonlinear optical
switches operating in the infrared. One may also be able to exploit t
he long mean free path in Sb (up to 2 mum) in studying quantum transpo
rt phenomena. X-ray diffraction confirms the ordered growth of GaSb/Sb
/GaSb multilayers, and field-dependent magnetotransport measurements y
ield electron and hole mobilities greater-than-or-equal-to 3 X 10(4) c
m2/V s in Sb thin films.