Dm. Kerrick et K. Caldeira, PALEOATMOSPHERIC CONSEQUENCES OF CO2 RELEASED DURING EARLY CENOZOIC REGIONAL METAMORPHISM IN THE TETHYAN OROGEN, Chemical geology, 108(1-4), 1993, pp. 201-230
The Eocene was the warmest epoch of the Cenozoic, with published estim
ates of Eocene atmospheric CO2 content ranging from two to six times t
he current value. Calculations of CO2 consumption by silicate weatheri
ng show that CO2 fluxes to the atmosphere of ca. 10(18)/Myr could acco
unt for inferred Paleocene/Eocene atmospheric CO2 contents, and the re
sulting greenhouse effect would have contributed to Eocene warmth. Ext
ensive portions of the Tethyan orogen underwent regional metamorphism
culminating in the Eocene. Prograde metamorphism may have been contemp
oraneous with the Late Paleocene global warming. We calculated the amo
unt of metamorphic CO2 produced at depth in the Himalayan orogen with
data on the timing of the India/Asia collision, duration of prograde r
egional metamorphism, and proportions and bulk compositions of metamor
phic CO2 source rocks. If CO2 was generated at a constant rate over a
10 Myr period of prograde metamorphism in the Himalayan orogen, we est
imate that ca. 10(18)-10(19) moles/Myr of metamorphic CO2 were produce
d al depth. Significant expulsion of metamorphic CO2 to the atmosphere
may have occurred by focused fluid flow along shear zones such as the
extensive Main Central Thrust in the Himalayan orogen. An additional
ca. 10(18)/Myr could have been contributed by Eocene regional metamorp
hism in the Mediterranean Tethys (i.e., from the Alps to Turkey). The
extensive metamorphism associated with the India/Asia collision, and t
he closing of Tethys, may have contributed to CO2-greenhouse warming i
n the early to mid Cenozoic.