ENANTIOSELECTIVE EPOXIDATION BY AN OPTICALLY-ACTIVE HYDROPEROXIDE

Authors
HAMANN HJ HOFT E CHMIELEWSKI M MACIEJEWSKI S
Citation
Hj. Hamann et al., ENANTIOSELECTIVE EPOXIDATION BY AN OPTICALLY-ACTIVE HYDROPEROXIDE, Chirality, 5(5), 1993, pp. 338-340
Citations number
16
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
Journal title
Chirality → ACNP
ISSN journal
08990042
Volume
5
Issue
5
Year of publication
1993
Pages
338 - 340
Database
ISI
SICI code
0899-0042(1993)5:5<338:EEBAOH>2.0.ZU;2-S
Abstract
Enantioselective epoxidation of prochiral allylic alcohols with optica lly active cetyl-2,3-dideoxy-alpha-D-threo-hex-2-enopyranosyl hydroper oxide in the presence of Ti(O-i-Pr)4 gives chiral epoxy alcohols with moderate enantiomeric excess. (C) 1993 Wiley-Liss, Inc.