PHOTOINITIATED REACTIONS OF ORGANIC-COMPOUNDS WITH METAL-COMPLEXES .26. PHOTOOXYGENATION OF CYCLOHEXANE BY ATMOSPHERIC OXYGEN IN METHYLENE-CHLORIDE, CATALYZED BY A CR(IV) OXOCOMPLEX

Authors
MUZART J DRUZHININA AN SHULPIN GB
Citation
J. Muzart et al., PHOTOINITIATED REACTIONS OF ORGANIC-COMPOUNDS WITH METAL-COMPLEXES .26. PHOTOOXYGENATION OF CYCLOHEXANE BY ATMOSPHERIC OXYGEN IN METHYLENE-CHLORIDE, CATALYZED BY A CR(IV) OXOCOMPLEX, Petroleum chemistry, 33(2), 1993, pp. 113-115
Citations number
15
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
2
Year of publication
1993
Pages
113 - 115
Database
ISI
SICI code
0965-5441(1993)33:2<113:PROOWM>2.0.ZU;2-P
Abstract
During the visible light irradiation in air of a solution of cyclohexa ne and a complex of Cr(IV) with pyridinium C5H5NHCrO3Cl in CH2Cl2, rou ghly equal quantities of cyclohexanol and cyclohexanone are formed (cy clohexylhydroperoxide is not found). A total of about eight molecules of the products per oxocomplex molecule are formed within 4 hr.