GAS-FORMATION DURING THE DECOMPOSITION OF PARAFFIN OXIDATE HYDROPEROXIDES

Authors
BORISOV IM ZIMIN YS MARTEMYANOV VS SIZOV NI
Citation
Im. Borisov et al., GAS-FORMATION DURING THE DECOMPOSITION OF PARAFFIN OXIDATE HYDROPEROXIDES, Petroleum chemistry, 33(2), 1993, pp. 131-134
Citations number
2
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
2
Year of publication
1993
Pages
131 - 134
Database
ISI
SICI code
0965-5441(1993)33:2<131:GDTDOP>2.0.ZU;2-P
Abstract
A study has been made of the formation of CO2, CO and H-2 during the d ecomposition of paraffin oxidate hydroperoxides (ROOH). It is shown th at the yield of carbon oxides and hydrogen amounts roughly to one thir d of the decomposed (ROOH). The two-stage nature of ROOH decomposition and CO2 and CO accumulation has been established. The effective rate constants of ''rapid'' and ''slow'' accumulation of gases has been cal culated.