LINEAR BUTADIENE DIMERS IN THE PRINS REACTION

Citation
Rf. Talipov et al., LINEAR BUTADIENE DIMERS IN THE PRINS REACTION, Petroleum chemistry, 33(2), 1993, pp. 143-145
Citations number
3
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
ISSN journal
09655441
Volume
33
Issue
2
Year of publication
1993
Pages
143 - 145
Database
ISI
SICI code
0965-5441(1993)33:2<143:LBDITP>2.0.ZU;2-H
Abstract
An investigation has been made of die reaction of butadiene dimers - 1 ,3.7-octatriene and 2-methyl-1,4,6-heptatriene - with formaldehyde und er conditions of the Prins reaction. It is shown that, depending on th e nature of the catalyst (H2SO4, BF3.O(C2H5)2), the reaction of butadi ene dimers with formaldehyde leads to a mixture of 1,3-dioxanes and di hydropyrans or only to the latter.