[[4-(N-TERT-BUTYL-N-HYDROXYAMINO)PHENYL]ACETYLENE] AND THE MAGNETIC PROPERTY OF ITS RADICAL DERIVATIVE

Authors
NISHIDE H KANEKO T YOSHIOKA N AKIYAMA H IGARASHI M TSUCHIDA E
Citation
H. Nishide et al., [[4-(N-TERT-BUTYL-N-HYDROXYAMINO)PHENYL]ACETYLENE] AND THE MAGNETIC PROPERTY OF ITS RADICAL DERIVATIVE, Macromolecules, 26(17), 1993, pp. 4567-4571
Citations number
37
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecules → ACNP
ISSN journal
00249297
Volume
26
Issue
17
Year of publication
1993
Pages
4567 - 4571
Database
ISI
SICI code
0024-9297(1993)26:17<4567:[ATMP>2.0.ZU;2-T
Abstract
[4-(N-tert-Butyl-N-hydroxyamino)phenyllacetylene (7) was synthesized a nd polymerized to yield a solvent-soluble polyacetylene: [[4-(N-tert-b utyl-N-hydroxyamino)phenyl]acetylene] (8). Oxidation of the polymer ga ve its radical derivative: the ESR spectrum showed a broad signal only in the DELTAm(s) = +/-1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.