THE CONVERSION OF CARBOXYLIC-ACIDS TO AMIDES VIA TIN(II) REAGENTS

Authors
BURNELLCURTY C ROSKAMP EJ
Citation
C. Burnellcurty et Ej. Roskamp, THE CONVERSION OF CARBOXYLIC-ACIDS TO AMIDES VIA TIN(II) REAGENTS, Tetrahedron letters, 34(33), 1993, pp. 5193-5196
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
33
Year of publication
1993
Pages
5193 - 5196
Database
ISI
SICI code
0040-4039(1993)34:33<5193:TCOCTA>2.0.ZU;2-O
Abstract
Unsymmetrical tin(II) amides can be generated, in situ, by adding one equivalent of an amine to bis(bistrimethylsilylamino) tin, Sn[N(TMS)2] 2. Treatment of carboxylic acids with these tin(II) reagents derived f rom alkyl or aryl amines results in smooth conversion to the correspon ding N-alkyl or N-aryl amides.