RADICAL-INDUCED EPOXIDE FRAGMENTATION CHEMISTRY .5. FORMATION OF MEDIUM-SIZED RINGS VIA BETA-SCISSION OF ALKOXY RADICALS

Authors
RAWAL VH ZHONG HM
Citation
Vh. Rawal et Hm. Zhong, RADICAL-INDUCED EPOXIDE FRAGMENTATION CHEMISTRY .5. FORMATION OF MEDIUM-SIZED RINGS VIA BETA-SCISSION OF ALKOXY RADICALS, Tetrahedron letters, 34(33), 1993, pp. 5197-5200
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
33
Year of publication
1993
Pages
5197 - 5200
Database
ISI
SICI code
0040-4039(1993)34:33<5197:REFC.F>2.0.ZU;2-3
Abstract
Functionalized medium-sized rings can be prepared from simple Robinson annulation derived precursors having a suitably placed stabilizing gr oup. The key step is a radical-induced epoxide fragmentation reaction followed by beta-scission of the resulting alkoxy radical.