A HIGHLY ELECTROPHILIC UNSATURATED DITUNGSTEN DICATION

Authors
ALVAREZ MA GARCIA ME RIERA V RUIZ MA BOIS C JEANNIN Y
Citation
Ma. Alvarez et al., A HIGHLY ELECTROPHILIC UNSATURATED DITUNGSTEN DICATION, Angewandte Chemie, International Edition in English, 32(8), 1993, pp. 1156-1157
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
8
Year of publication
1993
Pages
1156 - 1157
Database
ISI
SICI code
0570-0833(1993)32:8<1156:AHEUDD>2.0.ZU;2-H
Abstract
Through hydride or fluoride abstraction, the dication 1 reacts with BH 3 . THF (PF6-) to give monocationic complexes in which a hydrido (fluo ro) ligand bridges a W-W triple bond (W-W single bond). The unusually high electrophilicity of 1 arises from the combination of positive cha rge and metal-metal multiple bond. The counterion in each case is PF6- .