MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .122. METHYLTRIOXORHENIUM(VII) AS CATALYST FOR EPOXIDATIONS - STRUCTURE OFTHE ACTIVE SPECIES AND MECHANISM OF CATALYSIS

Authors
HERRMANN WA FISCHER RW SCHERER W RAUCH MU
Citation
Wa. Herrmann et al., MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .122. METHYLTRIOXORHENIUM(VII) AS CATALYST FOR EPOXIDATIONS - STRUCTURE OFTHE ACTIVE SPECIES AND MECHANISM OF CATALYSIS, Angewandte Chemie, International Edition in English, 32(8), 1993, pp. 1157-1160
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
8
Year of publication
1993
Pages
1157 - 1160
Database
ISI
SICI code
0570-0833(1993)32:8<1157:MBBMEA>2.0.ZU;2-K
Abstract
Explosive in the solid state, the bis(eta2-peroxo) complex 1, which in solution is the active species in the epoxidation of olefins with [CH 3ReO3]. could be characterized by X-ray crystallography as the diglyme adduct 2. Under catalytic conditions (excess of H2O2), 1 is far more stable than in the free state.