THE 1ST NEUTRAL ADAMANTANOID IRON(III)-CHELATE COMPLEX - SPONTANEOUS FORMATION, STRUCTURE, AND ELECTROCHEMISTRY

Authors
SAALFRANK RW HORNER B STALKE D SALBECK J
Citation
Rw. Saalfrank et al., THE 1ST NEUTRAL ADAMANTANOID IRON(III)-CHELATE COMPLEX - SPONTANEOUS FORMATION, STRUCTURE, AND ELECTROCHEMISTRY, Angewandte Chemie, International Edition in English, 32(8), 1993, pp. 1179-1182
Citations number
54
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
8
Year of publication
1993
Pages
1179 - 1182
Database
ISI
SICI code
0570-0833(1993)32:8<1179:T1NAIC>2.0.ZU;2-C
Abstract
''Metalloautism''-this term perfectly describes the characteristic of the adamantanoid iron(III) chelate complex 1 that the four iron center s do not interact with each other either electronically or magneticall y. The four metal atoms are linked by six chelatino ligands (2), which are prepared by deprotonation of the product of the condensation of t erephthaloyl chloride and dimethyl malonate.