DILITHIATION OF 2 DIPHENYL ETHERS EACH CONTAINING 2 NHCH2CH2Y (Y=OME,NME2) SIDE ARMS IN ORTHO POSITIONS - ASSEMBLY OF ADAMANTANOID LI4O2N4CORES

Authors
CRAGGHINE I DAVIDSON MG KOCIAN O MAIR FS POHL E RAITHBY PR SNAITH R SPENCER N STODDART JF
Citation
I. Cragghine et al., DILITHIATION OF 2 DIPHENYL ETHERS EACH CONTAINING 2 NHCH2CH2Y (Y=OME,NME2) SIDE ARMS IN ORTHO POSITIONS - ASSEMBLY OF ADAMANTANOID LI4O2N4CORES, Angewandte Chemie, International Edition in English, 32(8), 1993, pp. 1182-1184
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
8
Year of publication
1993
Pages
1182 - 1184
Database
ISI
SICI code
0570-0833(1993)32:8<1182:DO2DEE>2.0.ZU;2-A
Abstract
No N2Li2 units are formed on dilithiation of the RNH-substituted ether s 1 and 2. Instead. the dimerization of two monomers leads to adamanta noid structures with Li4O2N4 frameworks and CH2CH2OMe and CH2CH2NMe2 s ide arms that are crucial for dimer formation. The adamantanoid struct ure of the Li2 compound prepared from 1 also persists in solution.