METALLOMESOGENS WITH A CHOLESTERIC MESOPHASE

Authors
BAENA MJ BUEY J ESPINET P KITZEROW HS HEPPKE G
Citation
Mj. Baena et al., METALLOMESOGENS WITH A CHOLESTERIC MESOPHASE, Angewandte Chemie, International Edition in English, 32(8), 1993, pp. 1201-1203
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
8
Year of publication
1993
Pages
1201 - 1203
Database
ISI
SICI code
0570-0833(1993)32:8<1201:MWACM>2.0.ZU;2-#
Abstract
The combination of thiolato and carboxylato bridges in 1 force a cis a rrangement of the imine ligands unique for this type of complex. The c hiral dinuclear complexes 1 are mesogenic and in nematic solvents indu ce cholesteric phases having a temperature-dependent helical screw sen se. R' is for example C6H13.