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SYNTHESIS AND STRUCTURAL DETERMINATION OF A NEODYMIUM(III) COMPLEX DERIVED FROM OPENTADIENYL-1-METHYLETHYL)-9,10-DIHYDROANTHRACENE

Authors

CHAUVIN Y HEYWORTH S OLIVIER H ROBERT F SAUSSINE L

Citation

Y. Chauvin et al., SYNTHESIS AND STRUCTURAL DETERMINATION OF A NEODYMIUM(III) COMPLEX DERIVED FROM OPENTADIENYL-1-METHYLETHYL)-9,10-DIHYDROANTHRACENE, Journal of organometallic chemistry, 455(1-2), 1993, pp. 89-92

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear

Journal title

Journal of organometallic chemistry → ACNP

ISSN journal

0022328X

Volume

455

Issue

1-2

Year of publication

1993

Pages

89 - 92

Database

ISI

SICI code

0022-328X(1993)455:1-2<89:SASDOA>2.0.ZU;2-K

Abstract

Neodymium trichloride reacts with 2 equiv. of the lithium salt of open tadienyl-1-methylethyl)-9,10-dihydroanthracene in THF to give the ''at e'' complex [Li(THF)4][Nd{(C5H4)CMe2(C14H10)}2] which has been charact erized by its crystal structure and elemental analysis. The neodymium atom is situated in tetrahedral environment. It is eta5-bonded to the two cyclopentadienyl rings and sigma-bonded to the C(10) atoms of the two dihydroanthracene moieties.