UTILIZATION OF ME3SISNBU3 IN ORGANIC-SYNTHESIS .1. GENERATION OF A STANNYL ANION FROM ME3SISNBU3 AND R4NX

Authors
MORI M KANETA N ISONO N SHIBASAKI M
Citation
M. Mori et al., UTILIZATION OF ME3SISNBU3 IN ORGANIC-SYNTHESIS .1. GENERATION OF A STANNYL ANION FROM ME3SISNBU3 AND R4NX, Journal of organometallic chemistry, 455(1-2), 1993, pp. 255-260
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
455
Issue
1-2
Year of publication
1993
Pages
255 - 260
Database
ISI
SICI code
0022-328X(1993)455:1-2<255:UOMIO.>2.0.ZU;2-Q
Abstract
A metal free stannyl anion generated from Me3SiSnBu3 and R4NX in DMF r eacted with an aryl halide bearing carbonyl group to produce an aryl a nion via the so-called halogen-metal exchange process, which reacted w ith a carbonyl group to afford a cyclized product in good yield.