MONOMERIC ARSINOBORANES - THE QUESTION OF ARSENIC-BORON PI-BONDING

Authors
MARDONES MA COWLEY AH CONTRERAS L JONES RA CARRANO CJ
Citation
Ma. Mardones et al., MONOMERIC ARSINOBORANES - THE QUESTION OF ARSENIC-BORON PI-BONDING, Journal of organometallic chemistry, 455(1-2), 1993, pp. 30000001-30000002
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
455
Issue
1-2
Year of publication
1993
Pages
30000001 - 30000002
Database
ISI
SICI code
0022-328X(1993)455:1-2<30000001:MA-TQO>2.0.ZU;2-N
Abstract
The monomeric arsinoboranes R2AsB(MeS)2(R = (i)Pr (1); (t)Bu (2); Mes = mesityl) have been prepared via the reaction of LiAsR2 with MeS2BF i n Et2O solution; compound 1 has been characterized by X-ray crystallog raphy: monoclinic, space group P2(1)/c with a = 8.883(2), b = 29.190(6 ), c = 9.146(2) angstrom, beta = 100.46(3)-degrees, and Z = 4.